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Crown Ethers
Crown ethers are macrocyclic compounds containing equally spaced ether linkages in a large ring system. They readily form complexes with metal salts or ammonium salts. Depending on size, number and type of heteroatom, crown ethers can exhibit selectivity toward specific metal cations. For example, 12-crown-4 prefers to form complexes with Li+, whereas 18-crown-6 prefers K+. These crown-metal complexes are referred to as host-guest chemistry where the crown ether is the host and the metal cation is the guest.

Crown ethers are used to separate cations, dissolve inorganic salts into organic solvents to perform naked anion chemistry, serve as phase transfer catalysts, and chiral crown ethers have been used to resolve racemic mixtures or separate isomers by chiral chromatography.

Example compounds produced by Parish Chemical:
Benzo-15-crown-5
15-Crown-5
18-Crown-6
Cyclohexyl-15-crown-5
Dibenzo-18-crown-6 (below)
Dicyclohexyl-18-crown-6
Di-t-butyldibenzo-18-crown-6
This site is still under construction. Parish Chemical produces much more than the few products listed here. Please return as we update our product line.
 Structure   Name   Product #   CAS # 
 4,4กฏ(5กฏ)-Di-tert-butyldibenzo-24-crown-8   2902   [29471-17-8] 
 4-Aminobenzo-15-Crown-5   2928   [60835-71-4] 
 Benzo-15-Crown-5   1405   [14098-44-3] 
 Benzo-18-crown-6   1037   [14098-24-9] 
 4-tert-Butylbenzo-15-crown-5   1402   [15196-73-3] 
 4-tert-Butylcyclohexano-15-crown-5   1403   [17454-49-8] 
 18-Crown-6   2260   [17455-13-9] 
 Cyclohexano-15-crown-5   1404   [17454-48-7] 
 Di-2,3-naphtho-30-crown-10   2916   [98793-05-6] 
 4,4'(5')-Di-tert-butyldibenzo18-crown-6   1541   [29471-17-8] 
 4,4'-(5')-Di-tert-butyldicyclohexano-18-crown-6   1702   [38723-98-7] 
 4,4'(5')-Di-tert-butyldicyclohexano-24-crown-8   2903   [70936-93-5] 
 4,10-Diaza-15-crown-5   1715   [31249-95-3] 
 Dibenzo-18-crown-6   1350   [14187-32-7] 
 Dibenzo-21-crown-7   2636   [14098-41-0] 
 Dibenzo-24-crown-8   2261   [14174-09-5] 
 Dibenzo-30-crown-10   1423   [17455-25-3] 
 Dicyclohexano-18-crown-6, purified   2032   [16069-36-6] 
 Dicyclohexano-21-crown-7   2637   [17455-21-9] 
 Dicyclohexano-24-crown-8   2262   [17455-23-1] 
 2,6-Diketo-18-crown-6   3389   [62796-84-3] 
 2,3-Naphtho-15-crown-5   2915   [17454-47-6] 
 4'-Nitrobenzo-15-crown-5   2932   [60835-69-0] 
 Tetraaza-12-crown-4 tetrahydrochloride   1171   [10045-25-7] 
 Tetraaza-12-crown-4 tetrahydrogen sulfate   2649   [134765-72-3] 
 1,4,10,13-Tetraoxa-7,16-diazacyclooctadecane   3024   [23978-55-4] 
 12-crown-4   1816   [294-93-9] 
 15-crown-5, purified   2259   [33100-27-5] 
 21-crown-7   2631   [33089-36-0] 
More Crown Ethers...


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